Detection of Non-Random Galaxy Orientations in X-ray Subclusters of the Coma Cluster

This study on the Coma cluster suggests that there are deviations from a completely random galaxy orientation on small scales. Since we found a significant coincidence of hot-gas features identified in the latest X-ray observations of Coma with these local anisotropies, they may indicate regions of recent mutual interaction of member galaxies within subclusters which are currently falling in on the main cluster.Comment: 4 pages, 4 figures, 3 tables v2: Rewritten introduction, amendments to the 'Interpretation' sectio

Tree-ring stable isotopes and radiocarbon reveal pre- and post-eruption effects of volcanic processes on trees on Mt. Etna (Sicily, Italy)

Early detection of volcanic eruptions is of major importance for protecting human life. Ground deformation and changes in seismicity, geochemistry, petrology, and gravimetry are used to assess volcanic activity before eruptions. Studies on Mt. Etna (Italy) have demonstrated that vegetation can be affected by pre-eruptive activity before the onset of eruptions. During two consecutive years before Mt. Etna's 2002/2003 flank eruption, enhanced vegetation index (NDVI) values were detected along a distinct line which later developed into an eruptive fissure. However, the mechanisms by which volcanic activity can lead to changes in pre-eruption tree growth processes are still not well understood. We analysed ${\delta}^{13}$C, ${\delta}^{18}$O and $^{14}$C in the rings of the survived trees growing near to the line where the pre-eruptive increase in NDVI was observed in order to evaluate whether the uptake of water vapour or fossil volcanic CO2 could have contributed to the enhanced NDVI. We found a dramatic decrease in ${\delta}^{18}$O in tree rings formed before 2002/2003 in trees close to the eruption fissure, suggesting uptake of volcanic water by trees during pre-eruptive magma degassing. Moist conditions caused by outgassing of ascending magma may also have led to an observed reduction in tree-ring ${\delta}^{13}$C following the eruption. Furthermore, only ambiguous evidence for tree uptake of degassed CO2 was found. Our results suggest that additional soil water condensed from degassed water vapour may have promoted photosynthesis, explaining local increases in NDVI before the 2002/2003 Mt. Etna flank eruption. Tree-ring oxygen stable isotopes might be used as indicators of past volcanic eruptions

The influence of traffic and wood combustion on the stable isotopic composition of carbon monoxide

Carbon monoxide in the atmosphere is originating from various combustion and oxidation processes. Recently, the proportion of CO resulting from the combustion of wood for domestic heating may have increased due to political measures promoting this renewable energy source. Here, we used the stable isotope composition of CO (δ<sup>13</sup>C and δ<sup>18</sup>O) for the characterization of different CO sources in Switzerland, along with other indicators for traffic and wood combustion (NO<sub>x</sub>-concentration, aerosol light absorption at different wavelengths). We assessed diurnal variations of the isotopic composition of CO at 3 sites during winter: a village site dominated by domestic heating, a site close to a motorway and a rural site. The isotope ratios of wood combustion emissions were studied at a test facility, indicating significantly lower δ<sup>18</sup>O of CO from wood combustion compared to traffic emissions. At the village and the motorway site, we observed very pronounced diurnal δ<sup>18</sup>O-variations of CO with an amplitude of up to 8‰. Solving the isotope mass balance equation for three distinct sources (wood combustion, traffic, clean background air) resulted in diurnal patterns consistent with other indicators for wood burning and traffic. The average night-time contribution of wood-burning to total CO was 70% at the village site, 49% at the motorway site and 29% at the rural site based on the isotope mass balance. The results, however, depend strongly on the pure source isotope values, which are not very well known. We therefore additionally applied a combined CO/NO<sub>x</sub>-isotope model for verification. Here, we separated the CO emissions into different sources based on distinct CO/NO<sub>x</sub> emissions ratios for wood combustion and traffic, and inserted this information in the isotope mass balance equation. Accordingly, a highly significant agreement between measured and calculated δ<sup>18</sup>O-values of CO was found (<i>r</i>=0.67, <i>p</i><0.001). While different proxies for wood combustion all have their uncertainties, our results indicate that the oxygen isotope ratio of CO (but not the carbon isotope ratio) is an independent sensitive tool for source attribution studies

Technical note: On uncertainties in plant water isotopic composition following extraction by cryogenic vacuum distillation

Recent studies have challenged the interpretation of plant water isotopes obtained through cryogenic vacuum distillation (CVD) based on observations of a large 2H fractionation. These studies have hypothesized the existence of an H-atom exchange between water and organic tissue during CVD extraction with the magnitude of H exchange related to relative water content of the sample; however, clear evidence is lacking. Here, we systematically tested the uncertainties in the isotopic composition of CVD-extracted water by conducting a series of incubation and rehydration experiments using isotopically depleted water, water at natural isotope abundance, woody materials with exchangeable H, and organic materials without exchangeable H (cellulose triacetate and caffeine). We show that the offsets between hydrogen and oxygen isotope ratios and expected reference values (Δ2H and Δ18O) have inversely proportional relationships with the absolute amount of water being extracted, i.e. the lower the water amount, the higher the Δ2H and Δ18O. However, neither Δ2H nor Δ18O values, were related to sample relative water content. The Δ2H pattern was more pronounced for materials with exchangeable H atoms than with non-exchangeable H atoms. This is caused by the combined effect of H exchange during the incubation of materials in water and isotopic enrichments during evaporation and sublimation that depend on absolute water amount. The H exchange during CVD extraction itself was negligible. Despite these technical issues, we observed that the water amount-dependent patterns were much less pronounced for samples at natural isotope abundance and particularly low when sufficiently high amounts of water were extracted (&gt;600 µL). Our study provides new insights into the mechanisms causing isotope fractionation during CVD extraction of water. The methodological uncertainties can be controlled if large samples of natural isotope abundance are used in ecohydrological studies.</p

Technical Note: On Uncertainties in Plant Water Isotopic Composition Following Extraction by Cryogenic Vacuum Distillation

Recent studies have challenged the interpretation of plant water isotopes obtained through cryogenic vacuum distillation (CVD) based on observations of a large 2H fractionation. These studies have hypothesized the existence of an H-atom exchange between water and organic tissue during CVD extraction with the magnitude of H exchange related to relative water content of the sample; however, clear evidence is lacking. Here, we systematically tested the uncertainties in the isotopic composition of CVD-extracted water by conducting a series of incubation and rehydration experiments using isotopically depleted water, water at natural isotope abundance, woody materials with exchangeable H, and organic materials without exchangeable H (cellulose triacetate and caffeine). We show that the offsets between hydrogen and oxygen isotope ratios and expected reference values (Δ2H and Δ18O) have inversely proportional relationships with the absolute amount of water being extracted, i.e. the lower the water amount, the higher the Δ2H and Δ18O. However, neither Δ2H nor Δ18O values, were related to sample relative water content. The Δ2H pattern was more pronounced for materials with exchangeable H atoms than with non-exchangeable H atoms. This is caused by the combined effect of H exchange during the incubation of materials in water and isotopic enrichments during evaporation and sublimation that depend on absolute water amount. The H exchange during CVD extraction itself was negligible. Despite these technical issues, we observed that the water amount-dependent patterns were much less pronounced for samples at natural isotope abundance and particularly low when sufficiently high amounts of water were extracted (\u3e600 µL). Our study provides new insights into the mechanisms causing isotope fractionation during CVD extraction of water. The methodological uncertainties can be controlled if large samples of natural isotope abundance are used in ecohydrological studies

Impact of different nitrogen emission sources on tree physiology as assessed by a triple stable isotope approach

The importance that nitrogen (N) deposition has in driving the carbon (C) sequestration of forests has recently been investigated using both experimental and modeling approaches. Whether increased N deposition has positive or negative effects on such ecosystems depends on the status of the N and the duration of the deposition. By combining d13C, d18O, d15N and dendrochronological approaches, we analyzed the impact of two different sources of NOx emissions on two tree species, namely: a broadleaved species (Quercus cerris) that was located close to an oil refinery in Southern Italy, and a coniferous species (Picea abies) located close to a freeway in Switzerland. Variations in the ci/ca ratio and the distinction between stomatal and photosynthetic responses to NOx emissions in trees were assessed using a conceptual model, which combines d13C and d18O. d15N in leaves, needles and tree rings was found to be a bioindicator of N input from anthropogenic emissions, especially at the oil refinery site.We observed that N fertilization had a stimulatory effect on tree growth near the oil refinery, while the opposite effect was found for trees at the freeway site. Changes in the ci/ca ratio were mostly related to variations in d13C at the freeway site and, thus, were driven by photosynthesis. At the oil refinery site they were mainly related to stomatal conductance, as assessed using d18O. This study demonstrates that a single method approach does not always provide a complete picture of which physiological traits are more affected by N emissions. The triple isotope approach combined with dendrochronological analyses proved to be a very promising tool for monitoring the ecophysiological responses of trees to long-term N deposition